MODEL 926 CHLORIDE ANALYZER
Key Applications Areas
Principles of Method
The Sherwood Model 926 is used for the determination of chloride
ions. It is an instrumental analogue of "Argentimetry", the traditional
titrimetric methods using silver nitrate reagent. Like these classic
methods it relies on the chemical formation of the very insoluble salt,
The importance of chloride determination has been realized for well over a century, with many
variations and changes being made to the techniques in order to improve the detectability and
selectivity. Research into the analysis of chloride was conducted by Gay-Lussac (1832), Levol
(1853), Mohr (1856) and Volhard(1874) and their findings have proven to be the basis of the
methods which are still in common use today.
KEY APPLICATION AREAS
The measurement of Salt (Sodium Chloride) concentration in the Food and Dairy Industry is
universal. The ability to read direct in Salt concentration makes the Sherwood Model 926
the instrument of choice for manufacturers and food analysts around the world.
Salt and salinity also represents serious contamination in Industrial processes and the
sensitivity of the coulometric method enables measurement in the ppm range in boiler feed
water, polymer washes. bore hole slurries, as well as soils analysis and others. The 926
has proven itself to be the method of choice for many desalination studies and general
quality control of sample lines.
Clinical measurement of the chloride ion is
essential for monitoring of electrolyte balance of patients as it plays,
in combination with sodium and potassium, an important part in
maintaining water balance between cells, plasma and interstitial fluid.
The Model 926s is also widely used
in the confirmation of the diagnosis of Cystic Fibrosis.
The model 926S variant can accept 20 microlitre samples.
Sherwood Scientific has method notes for these and other Applications. Pharmaceutical
Production, Cement Manufacture, Photography Veterinary.
PRINCIPLES OF METHOD
The main difficulties with the classic method were that silver nitrate reagent would change
on storage due to a photochemical reaction and that the titration end point is visually weak.
The reagent would have to be standardized requiring a highly skilled analytical technician
The 926 method is based on a coulometric titration and is an absolute method where the reagent,
the silver ions, is precisely and quantitatively generated at the time of the analysis by
passing a constant current between donor electrodes. The end point is detected by the use of
sensing electrodes which measure the change in solution conductivity which occurs when excess
silver ions are present in solution.
| Specification || Model 926 || Model 926S |
| Sample size || 500 microlitres || 20 microlitres |
| Readout Range || 10-999mg Cl/l; 2-165mg%Salt || 10-299mmolCl/l |
| Analysis Time || 35 sec @ 200mgl/l || 35 sec@ 100mmolCl/l |
| Accuracy || SD <1% @ 0.1% Cl Std Solution || +-2% @ NQCS 100mmol/l |
| Linearity || 1% in range 10-999mgCl/l || 1% 10-299 mmolCl/l |
| Reproducibility CV for 20 replicates || <1.5% @ 200mgCl/l || <1.5% @ 100mmolCl/l |
The Sherwood Buffer system is optimised to eliminate interfering ions and
incorporates a special dispersant to ensure reproducible formation of the silver chloride
precipitate and enhance analytical performance.
The Sherwood Advantage
- The coulometric method is very robust and versatile
- The Sherwood microprocessor based Instrument is ergonomically designed and easy to use and maintain
- The Sherwood Buffer System specifically designed for the model 926 gives outstanding sensitivity and selectivity